Araştırma Makalesi
BibTex RIS Kaynak Göster
Yıl 2020, Cilt: 3 Sayı: 1, 20 - 27, 31.03.2020
https://doi.org/10.35208/ert.698720

Öz

Kaynakça

  • [1] R. Allmann, Magnesium aluminum carbonate hydroxide tetrahydrate: a discussion, American Mineralogist: Journal of Earth and Planetary Materials, 53 (1968) 1057-1059. [2] H. Taylor, Crystal structures of some double hydroxide minerals, Mineralogical Magazine, 39 (1973) 377-389. [3] A.L. McKenzie, C.T. Fishel, R.J. Davis, Investigation of the surface structure and basic properties of calcined hydrotalcites, Journal of Catalysis, 138 (1992) 547-561. [4] R. Allmann, The crystal structure of pyroaurite, Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry, 24 (1968) 972-977. [5] W. Reichle, S. Kang, D. Everhardt, The nature of the thermal decomposition of a catalytically active anionic clay mineral, Journal of Catalysis, 101 (1986) 352-359. [6] K. Hashi, S. Kikkawa, M. Koizumi, Preparation and properties of pyroaurite-like hydroxy minerals, Clays and Clay Minerals, 31 (1983) 152-154. [7] R. Taylor, H.C.B. Hansen, G. Stanger, C.B. Koch, On the genesis and composition of natural pyroaurite, Clay Minerals, 26 (1991) 297-309. [8] H.C.B. Hansen, C.B. Koch, Synthesis and characterization of pyroaurite, Applied clay science, 10 (1995) 5-19. [9] S. Miyata, Physico-chemical properties of synthetic hydrotalcites in relation to composition, Clays and Clay minerals, 28 (1980) 50-56. [10] M.a.A. Aramendı́a, Y. Avilés, J.A. Benı́tez, V. Borau, C. Jiménez, J.M. Marinas, J.R. Ruiz, F.J. Urbano, Comparative study of Mg/Al and Mg/Ga layered double hydroxides, Microporous and mesoporous materials, 29 (1999) 319-328. [11] S. Mancipe, F. Tzompantzi, H. Rojas, R. Gómez, Photocatalytic degradation of phenol using MgAlSn hydrotalcite-like compounds, Applied Clay Science, 129 (2016) 71-78. [12] T. Yoshioka, T. Kameda, M. Miyahara, M. Uchida, T. Mizoguchi, A. Okuwaki, Removal of tetrafluoroborate ion from aqueous solution using magnesium–aluminum oxide produced by the thermal decomposition of a hydrotalcite-like compound, Chemosphere, 69 (2007) 832-835. [13] H. Zhang, J. Wang, B. Zhang, Q. Liu, S. Li, H. Yan, L. Liu, Synthesis of a hydrotalcite-like compound from oil shale ash and its application in uranium removal, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 444 (2014) 129-137. [14] L. Châtelet, J. Bottero, J. Yvon, A. Bouchelaghem, Competition between monovalent and divalent anions for calcined and uncalcined hydrotalcite: anion exchange and adsorption sites, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 111 (1996) 167-175. [15] R.K. Kukkadapu, M.S. Witkowski, J.E. Amonette, Synthesis of a low-carbonate high-charge hydrotalcite-like compound at ambient pressure and atmosphere, Chemistry of materials, 9 (1997) 417-419. [16] S. Miyata, The Syntheses of Hydrotalcite-Like Compounds and Their Structures and Physico-Chemical Properties—I: the Systems Mg 2+-Al 3+-NO 3−, Mg 2+-Al 3+-Cl−, Mg 2+-Al 3+-ClO 4−, Ni 2+-Al 3+-Cl− and Zn 2+-Al 3+-Cl−, Clays and Clay Minerals, 23 (1975) 369-375. [17] R. Taylor, The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis, Clay Minerals, 19 (1984) 591-603. [18] L.M. Parker, N.B. Milestone, R.H. Newman, The use of hydrotalcite as an anion absorbent, Industrial & engineering chemistry research, 34 (1995) 1196-1202. [19] S. Miyata, Anion-exchange properties of hydrotalcite-like compounds, Clays and Clay minerals, 31 (1983) 305-311. [20] W.J.M. Chibwe, The Synthesis, Chemistry and Catalytic Applications of Layered Double Hydroxides, in: I.V. Mitchell (Ed.) Pillared Layered Structures – Current Trends and Application, Elsevier Science Publishers, England, 1990. [21] S. Carlino, Chemistry between the sheets, Chemistry in Britain, 33 (1997) 59-62. [22] A. Vaccari, Clays and catalysis: a promising future, Applied Clay Science, 14 (1999) 161-198. [23] N. Lazaridis, K. Matis, M. Webb, Flotation of metal-loaded clay anion exchangers. Part I: the case of chromates, Chemosphere, 42 (2001) 373-378. [24] L.-X. Zhao, J.-L. Liang, N. Li, H. Xiao, L.-Z. Chen, R.-S. Zhao, Kinetic, thermodynamic, and isotherm investigations of Cu2+ and Zn2+ adsorption on LiAl hydrotalcite-like compound, Science of The Total Environment, (2020) 137120. [25] G. Önkal-Engin, R. Wibulswas, D. White, Humic acid uptake from aqueous media using hydrotalcites and modified montmorillonite, Environmental technology, 21 (2000) 167-175. [26] J. Orthman, H. Zhu, G. Lu, Use of anion clay hydrotalcite to remove coloured organics from aqueous solutions, Sep Purif Technol, 31 (2003) 53-59. [27] M. Xu, G. Pan, Y. Meng, Y. Guo, T. Wu, H. Chen, Effect of Ce3+ on the photocatalytic activity of MAlCe ternary hydrotalcites-like compounds in methylene blue photodegradation, Applied Clay Science, 170 (2019) 46-56. [28] S. Zhao, H. Yi, X. Tang, D. Kang, F. Gao, J. Wang, Y. Huang, Z. Yang, Calcined ZnNiAl hydrotalcite-like compounds as bifunctional catalysts for carbonyl sulfide removal, Catalysis Today, 327 (2019) 161-167. [29] W.T. Reichle, Catalytic reactions by thermally activated, synthetic, anionic clay minerals, Journal of Catalysis, 94 (1985) 547-557. [30] L. Kolarik, N. Anderson, B.A. Bolto, C. Chin, A. Priestley, Magnetic microparticles in water treatment, (1994). [31] D. White, G. Onkal-Engin, R. Wibulswas, Simulation of the errors in equilibrium correlations using the langmuir and BET isotherms, Separation Science and Technology, 35 (2000) 367-377. [32] H.-S. Shin, M.-J. Kim, S.-Y. Nam, H.-C. Moon, Phosphorus removal by hydrotalcite-like compounds (HTLcs), Water Science and Technology, 34 (1996) 161-168. [33] S. Rhee, M. Kang, H. Kim, C. Moon, Removal of aquatic chromate ion involving rehydration reaction of calcined layered double hydroxide (Mg-Al-CO3), Environmental technology, 18 (1997) 231-236. [34] M. Lehmann, A. Zouboulis, K. Matis, Removal of metal ions from dilute aqueous solutions: a comparative study of inorganic sorbent materials, Chemosphere, 39 (1999) 881-892. [35] R.V. Gaines, H.C.W. Skinner;, E.E. Foord;, B. Mason;, A. Rosenzweig, Dana’s New Mineralogy, 8th ed ed., John Wiley and Sons, Inc., Surrey, England, 1997. [36] B. Houri, A. Legrouri, A. Barroug, C. Forano, J.-P. Besse, Use of the ion-exchange properties of layered double hydroxides for water purification, Collection of Czechoslovak chemical communications, 63 (1998) 732-740. [37] R.K. Kukkadapu, S.A. Boyd, Tetramethylphosphonium-and tetramethylammonium-smectites as adsorbents of aromatic and chlorinated hydrocarbons: effect of water on adsorption efficiency, Clays and Clay Minerals, 43 (1995) 318-323. [38] P.A. Webb, C. Orr, Analytical methods in fine particle technology, Micromeritics Instrument Corp, 1997. [39] M. Pourbaix, Atlas of electrochemical equilibria in aqueous solutions, NACE, (1966). [40] J. HUHEEY, E. KEITER, R. KEITER, Coordination chemistry: reactions, kinetics and mechanisms, Inorganic chemistry: principles of structure and reactivity. 4th ed. New York: HarperCollins College Publishers, 4 (1993) 537-576.

An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems

Yıl 2020, Cilt: 3 Sayı: 1, 20 - 27, 31.03.2020
https://doi.org/10.35208/ert.698720

Öz

The main aim of this study is to investigate the feasibility of utilising novel hydrotalcite-like-compounds as ion-exchangers for the removal of anionic impurities from aqueous solution. Hydrotalcite is naturally occurring, rarely found anionic clay. It has a positively charged layered structure consisting of two metal oxide layers and an interlayer of carbonate anions. Hydrotalcites can, therefore, be used as ion-exchangers. However, the carbonate anion is highly selected by natural hydrotalcite, making the ion-exchange capacity for other anions very low. In this study, several synthetic hydrotalcite-like compounds and a magnetic hydrotalcite-like compound samples were prepared in order to remove anionic impurities from waters. The physical structure and chemical properties of these anionic clays were characterised using standard characterisation techniques. The removal capacities of the synthetic products obtained were then investigated. Magnetic hydrotalcite-like-compound, namely, CaII-FeII-FeIII, was proved to be a good ion-exchanger.

Kaynakça

  • [1] R. Allmann, Magnesium aluminum carbonate hydroxide tetrahydrate: a discussion, American Mineralogist: Journal of Earth and Planetary Materials, 53 (1968) 1057-1059. [2] H. Taylor, Crystal structures of some double hydroxide minerals, Mineralogical Magazine, 39 (1973) 377-389. [3] A.L. McKenzie, C.T. Fishel, R.J. Davis, Investigation of the surface structure and basic properties of calcined hydrotalcites, Journal of Catalysis, 138 (1992) 547-561. [4] R. Allmann, The crystal structure of pyroaurite, Acta Crystallographica Section B: Structural Crystallography and Crystal Chemistry, 24 (1968) 972-977. [5] W. Reichle, S. Kang, D. Everhardt, The nature of the thermal decomposition of a catalytically active anionic clay mineral, Journal of Catalysis, 101 (1986) 352-359. [6] K. Hashi, S. Kikkawa, M. Koizumi, Preparation and properties of pyroaurite-like hydroxy minerals, Clays and Clay Minerals, 31 (1983) 152-154. [7] R. Taylor, H.C.B. Hansen, G. Stanger, C.B. Koch, On the genesis and composition of natural pyroaurite, Clay Minerals, 26 (1991) 297-309. [8] H.C.B. Hansen, C.B. Koch, Synthesis and characterization of pyroaurite, Applied clay science, 10 (1995) 5-19. [9] S. Miyata, Physico-chemical properties of synthetic hydrotalcites in relation to composition, Clays and Clay minerals, 28 (1980) 50-56. [10] M.a.A. Aramendı́a, Y. Avilés, J.A. Benı́tez, V. Borau, C. Jiménez, J.M. Marinas, J.R. Ruiz, F.J. Urbano, Comparative study of Mg/Al and Mg/Ga layered double hydroxides, Microporous and mesoporous materials, 29 (1999) 319-328. [11] S. Mancipe, F. Tzompantzi, H. Rojas, R. Gómez, Photocatalytic degradation of phenol using MgAlSn hydrotalcite-like compounds, Applied Clay Science, 129 (2016) 71-78. [12] T. Yoshioka, T. Kameda, M. Miyahara, M. Uchida, T. Mizoguchi, A. Okuwaki, Removal of tetrafluoroborate ion from aqueous solution using magnesium–aluminum oxide produced by the thermal decomposition of a hydrotalcite-like compound, Chemosphere, 69 (2007) 832-835. [13] H. Zhang, J. Wang, B. Zhang, Q. Liu, S. Li, H. Yan, L. Liu, Synthesis of a hydrotalcite-like compound from oil shale ash and its application in uranium removal, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 444 (2014) 129-137. [14] L. Châtelet, J. Bottero, J. Yvon, A. Bouchelaghem, Competition between monovalent and divalent anions for calcined and uncalcined hydrotalcite: anion exchange and adsorption sites, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 111 (1996) 167-175. [15] R.K. Kukkadapu, M.S. Witkowski, J.E. Amonette, Synthesis of a low-carbonate high-charge hydrotalcite-like compound at ambient pressure and atmosphere, Chemistry of materials, 9 (1997) 417-419. [16] S. Miyata, The Syntheses of Hydrotalcite-Like Compounds and Their Structures and Physico-Chemical Properties—I: the Systems Mg 2+-Al 3+-NO 3−, Mg 2+-Al 3+-Cl−, Mg 2+-Al 3+-ClO 4−, Ni 2+-Al 3+-Cl− and Zn 2+-Al 3+-Cl−, Clays and Clay Minerals, 23 (1975) 369-375. [17] R. Taylor, The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis, Clay Minerals, 19 (1984) 591-603. [18] L.M. Parker, N.B. Milestone, R.H. Newman, The use of hydrotalcite as an anion absorbent, Industrial & engineering chemistry research, 34 (1995) 1196-1202. [19] S. Miyata, Anion-exchange properties of hydrotalcite-like compounds, Clays and Clay minerals, 31 (1983) 305-311. [20] W.J.M. Chibwe, The Synthesis, Chemistry and Catalytic Applications of Layered Double Hydroxides, in: I.V. Mitchell (Ed.) Pillared Layered Structures – Current Trends and Application, Elsevier Science Publishers, England, 1990. [21] S. Carlino, Chemistry between the sheets, Chemistry in Britain, 33 (1997) 59-62. [22] A. Vaccari, Clays and catalysis: a promising future, Applied Clay Science, 14 (1999) 161-198. [23] N. Lazaridis, K. Matis, M. Webb, Flotation of metal-loaded clay anion exchangers. Part I: the case of chromates, Chemosphere, 42 (2001) 373-378. [24] L.-X. Zhao, J.-L. Liang, N. Li, H. Xiao, L.-Z. Chen, R.-S. Zhao, Kinetic, thermodynamic, and isotherm investigations of Cu2+ and Zn2+ adsorption on LiAl hydrotalcite-like compound, Science of The Total Environment, (2020) 137120. [25] G. Önkal-Engin, R. Wibulswas, D. White, Humic acid uptake from aqueous media using hydrotalcites and modified montmorillonite, Environmental technology, 21 (2000) 167-175. [26] J. Orthman, H. Zhu, G. Lu, Use of anion clay hydrotalcite to remove coloured organics from aqueous solutions, Sep Purif Technol, 31 (2003) 53-59. [27] M. Xu, G. Pan, Y. Meng, Y. Guo, T. Wu, H. Chen, Effect of Ce3+ on the photocatalytic activity of MAlCe ternary hydrotalcites-like compounds in methylene blue photodegradation, Applied Clay Science, 170 (2019) 46-56. [28] S. Zhao, H. Yi, X. Tang, D. Kang, F. Gao, J. Wang, Y. Huang, Z. Yang, Calcined ZnNiAl hydrotalcite-like compounds as bifunctional catalysts for carbonyl sulfide removal, Catalysis Today, 327 (2019) 161-167. [29] W.T. Reichle, Catalytic reactions by thermally activated, synthetic, anionic clay minerals, Journal of Catalysis, 94 (1985) 547-557. [30] L. Kolarik, N. Anderson, B.A. Bolto, C. Chin, A. Priestley, Magnetic microparticles in water treatment, (1994). [31] D. White, G. Onkal-Engin, R. Wibulswas, Simulation of the errors in equilibrium correlations using the langmuir and BET isotherms, Separation Science and Technology, 35 (2000) 367-377. [32] H.-S. Shin, M.-J. Kim, S.-Y. Nam, H.-C. Moon, Phosphorus removal by hydrotalcite-like compounds (HTLcs), Water Science and Technology, 34 (1996) 161-168. [33] S. Rhee, M. Kang, H. Kim, C. Moon, Removal of aquatic chromate ion involving rehydration reaction of calcined layered double hydroxide (Mg-Al-CO3), Environmental technology, 18 (1997) 231-236. [34] M. Lehmann, A. Zouboulis, K. Matis, Removal of metal ions from dilute aqueous solutions: a comparative study of inorganic sorbent materials, Chemosphere, 39 (1999) 881-892. [35] R.V. Gaines, H.C.W. Skinner;, E.E. Foord;, B. Mason;, A. Rosenzweig, Dana’s New Mineralogy, 8th ed ed., John Wiley and Sons, Inc., Surrey, England, 1997. [36] B. Houri, A. Legrouri, A. Barroug, C. Forano, J.-P. Besse, Use of the ion-exchange properties of layered double hydroxides for water purification, Collection of Czechoslovak chemical communications, 63 (1998) 732-740. [37] R.K. Kukkadapu, S.A. Boyd, Tetramethylphosphonium-and tetramethylammonium-smectites as adsorbents of aromatic and chlorinated hydrocarbons: effect of water on adsorption efficiency, Clays and Clay Minerals, 43 (1995) 318-323. [38] P.A. Webb, C. Orr, Analytical methods in fine particle technology, Micromeritics Instrument Corp, 1997. [39] M. Pourbaix, Atlas of electrochemical equilibria in aqueous solutions, NACE, (1966). [40] J. HUHEEY, E. KEITER, R. KEITER, Coordination chemistry: reactions, kinetics and mechanisms, Inorganic chemistry: principles of structure and reactivity. 4th ed. New York: HarperCollins College Publishers, 4 (1993) 537-576.
Toplam 1 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Çevre Mühendisliği
Bölüm Research Articles
Yazarlar

Güleda Engin 0000-0002-3841-8440

Hanife Sarı Erkan 0000-0003-1701-6482

David A. White Bu kişi benim

Yayımlanma Tarihi 31 Mart 2020
Gönderilme Tarihi 4 Mart 2020
Kabul Tarihi 16 Mart 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 3 Sayı: 1

Kaynak Göster

APA Engin, G., Sarı Erkan, H., & White, D. A. (2020). An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems. Environmental Research and Technology, 3(1), 20-27. https://doi.org/10.35208/ert.698720
AMA Engin G, Sarı Erkan H, White DA. An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems. ERT. Mart 2020;3(1):20-27. doi:10.35208/ert.698720
Chicago Engin, Güleda, Hanife Sarı Erkan, ve David A. White. “An Investigation on the Application of CaII-FeII-FeIII Magnetic Hydrotalcite-Like-Compounds for the Removal of Impurities in Aqueous Systems”. Environmental Research and Technology 3, sy. 1 (Mart 2020): 20-27. https://doi.org/10.35208/ert.698720.
EndNote Engin G, Sarı Erkan H, White DA (01 Mart 2020) An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems. Environmental Research and Technology 3 1 20–27.
IEEE G. Engin, H. Sarı Erkan, ve D. A. White, “An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems”, ERT, c. 3, sy. 1, ss. 20–27, 2020, doi: 10.35208/ert.698720.
ISNAD Engin, Güleda vd. “An Investigation on the Application of CaII-FeII-FeIII Magnetic Hydrotalcite-Like-Compounds for the Removal of Impurities in Aqueous Systems”. Environmental Research and Technology 3/1 (Mart 2020), 20-27. https://doi.org/10.35208/ert.698720.
JAMA Engin G, Sarı Erkan H, White DA. An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems. ERT. 2020;3:20–27.
MLA Engin, Güleda vd. “An Investigation on the Application of CaII-FeII-FeIII Magnetic Hydrotalcite-Like-Compounds for the Removal of Impurities in Aqueous Systems”. Environmental Research and Technology, c. 3, sy. 1, 2020, ss. 20-27, doi:10.35208/ert.698720.
Vancouver Engin G, Sarı Erkan H, White DA. An investigation on the application of CaII-FeII-FeIII magnetic hydrotalcite-like-compounds for the removal of impurities in aqueous systems. ERT. 2020;3(1):20-7.