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Year 2020, Volume: 5 Issue: 2, 34 - 42, 16.10.2020

Sevim Yolcular Karaoğlu

Abstract

References

  • [1] Chen X, Zhao Z, Liu X, Hao M, Tang Z, Chen A. Hydrogen generation by the hydrolysis reaction of ball-milled aluminium-lithium alloys. J. Power Sources 2014; 254: 345-352.
  • [2] Yolcular S, Karaoglu S. Activation of Al powder with NaCl assisted milling for hydrogen generation. Energy Sources Part A 2017; 39(18): 1919-1927.
  • [3] Liu Y, Ge H, Wang X, Liu H, Dong Z, Li S, Yan M. Study on hydrogen generation from the hydrolysis of a ball milled aluminum/calcium hydride composite. RSC Advances 2015; 5: 60460-60466.
  • [4] Olivares-Ramírez J.M, Marroquín de Jesús Á, Jiménez-Sandoval O, Pless R.C. Hydrogen Generation by Treatment of Aluminium Metal with Aqueous Solutions: Procedures and Uses, Hydrogen Energy - Challenges and Perspectives. Dragica Minic, IntechOpen, DOI: 10.5772/48762 , 2012.
  • [5] Soler L, Candela A. M., Macanas J, Munoz M, Casado J. Hydrogen generation by aluminum corrosion in seawater promoted by suspensions of aluminum hydroxide. Int. J. Hydrogen Energy 2009; 34: 8511–8518.
  • [6] Jiaa Y, Shena J, Menga H, Donga Y, Chaia Y, Wang N. Hydrogen generation using a ball-milled Al/Ni/NaCl mixture. J. Alloys Compd. 2014; 588: 259–264.
  • [7] Porciúncula CB, Marcilio NR, Tessaro IC, Gerchmann M. Production of hydrogen in the reaction between aluminum and water in the presence of NaOH and KOH. Braz. J. Chem. Eng. 2012; 29(2): 337-348.
  • [8] Kanehira S, Kanamori S, Nagashima K, Saeki T, Visbal H, Fukui T, Hirao K. Controllable hydrogen release via aluminum powder corrosion in calcium hydroxide solutions. J Asian Ceram. Soc. 2013;1(3):296-303.
  • [9] Yang BC, Chai YJ, Yang FL, Zhang Q, Liu H, Wang N. Hydrogen generation by aluminum‐water reaction in acidic and alkaline media and its reaction Dynamics. Int. J. Energy Res. 2018; 42: 1594-1602.
  • [10] Ziebarth JT, Woodall JM, Kramer RA, Choi G. Liquid phase‐enabled reaction of Al–Ga and Al–Ga–In–Sn alloys with water. Int. J. Hydrogen Energy 2011; 36(9): 5271‐5279.
  • [11] Chen XY, Zhao ZW, Hao MM, Wang DZ. Research of hydrogen generation by the reaction of Al-based materials with water. J. Power Sources 2013; 222: 188-195.
  • [12] Macanás J, Soler L, Candela AM, Muñoz M, Casado J. Hydrogen generation by aluminum corrosion in aqueous alkaline solutions of inorganic promoters: the AlHidrox process. Energy. 2011; 36(5):2493‐2501.
  • [13] Czech E, Troczynski T. Hydrogen generation through massive corrosion of deformed aluminum in water. Int. J. Hydrogen Energy 2010; 35: 1029-1037.
  • [14] Rong S, Baozhong Z, Yunlan S. The effect of NiCl2 and Na2CO3 on hydrogen production by Al/H2O system. Int. J. Hydrogen Energy 2017; 42: 3586-3592.
  • [15] Rosenband V, Gany A. Application of activated aluminum powder for generation of hydrogen from water Int. J. Hydrogen Energy 2010; 35: 10898-10904.
  • [16] Deng Z-Y, Ferreira J, Sakka Y. Hydrogen‐Generation Materials for Portable Applications. J. Am. Ceram. Soc. 2008; 91(12): 3825 – 3834.
  • [17] Chen XY, Zhao ZW, Hao MM, Wang DZJ. Research of hydrogen generation by the reaction of Al-based materials with water. J. Power Sources 2013; 222: 188–195.
  • [18] Fan MQ, Mei DS, Chen D, Lv CJ, Shu KY. Portable hydrogen generation from activated Al-Li-Bi alloys in water. Renewable Energy 2011; 36(11): 3061-3067.
  • [19] Li, R., Fang, Y., Yang, T., Sun, Y., Li, Y., 2011. Influence Factor of hydrogen generation from aluminum-water reaction. In: 2011 International conference on Computer distributed Control and Intelligent Environmental Monitoring; 19-20 Feb. 2011; Changsha, China. IEEE. pp. 852-855.
  • [20] Soler L, Macanas J, Munoz M, Casado J, Aluminum and aluminum alloys as sources of hydrogen for fuel cell applications. J. Power Sources 2007; 169: 144–149.

EFFECT OF ALKALINE CONCENTRATION ON THE HYDROGEN GENERATION

Year 2020, Volume: 5 Issue: 2, 34 - 42, 16.10.2020

Sevim Yolcular Karaoğlu

Abstract

Al water reaction is one of the preferred hydrogen production methods. However, the passive oxide film which forms on the surface of Al particles that prevents or delays the reaction during this reaction is a problem. In this study, in order to overcome this problem ball milling was applied and NaOH solutions with different concentrations were used in the reactions. Al powders were ball milled with NaCl and 0.5, 1, 1.5, 2 M NaOH solutions were used in the experiments. Effect of alkaline concentration was investigated on the hydrogen generation experiments. The results showed that, higher temperatures and increased concentrations of NaOH solutions improves the hydrogen generation rate.

Keywords

Hydrogen generation Al powder Al water reaction ball milling NaOH concentration

References

  • [1] Chen X, Zhao Z, Liu X, Hao M, Tang Z, Chen A. Hydrogen generation by the hydrolysis reaction of ball-milled aluminium-lithium alloys. J. Power Sources 2014; 254: 345-352.
  • [2] Yolcular S, Karaoglu S. Activation of Al powder with NaCl assisted milling for hydrogen generation. Energy Sources Part A 2017; 39(18): 1919-1927.
  • [3] Liu Y, Ge H, Wang X, Liu H, Dong Z, Li S, Yan M. Study on hydrogen generation from the hydrolysis of a ball milled aluminum/calcium hydride composite. RSC Advances 2015; 5: 60460-60466.
  • [4] Olivares-Ramírez J.M, Marroquín de Jesús Á, Jiménez-Sandoval O, Pless R.C. Hydrogen Generation by Treatment of Aluminium Metal with Aqueous Solutions: Procedures and Uses, Hydrogen Energy - Challenges and Perspectives. Dragica Minic, IntechOpen, DOI: 10.5772/48762 , 2012.
  • [5] Soler L, Candela A. M., Macanas J, Munoz M, Casado J. Hydrogen generation by aluminum corrosion in seawater promoted by suspensions of aluminum hydroxide. Int. J. Hydrogen Energy 2009; 34: 8511–8518.
  • [6] Jiaa Y, Shena J, Menga H, Donga Y, Chaia Y, Wang N. Hydrogen generation using a ball-milled Al/Ni/NaCl mixture. J. Alloys Compd. 2014; 588: 259–264.
  • [7] Porciúncula CB, Marcilio NR, Tessaro IC, Gerchmann M. Production of hydrogen in the reaction between aluminum and water in the presence of NaOH and KOH. Braz. J. Chem. Eng. 2012; 29(2): 337-348.
  • [8] Kanehira S, Kanamori S, Nagashima K, Saeki T, Visbal H, Fukui T, Hirao K. Controllable hydrogen release via aluminum powder corrosion in calcium hydroxide solutions. J Asian Ceram. Soc. 2013;1(3):296-303.
  • [9] Yang BC, Chai YJ, Yang FL, Zhang Q, Liu H, Wang N. Hydrogen generation by aluminum‐water reaction in acidic and alkaline media and its reaction Dynamics. Int. J. Energy Res. 2018; 42: 1594-1602.
  • [10] Ziebarth JT, Woodall JM, Kramer RA, Choi G. Liquid phase‐enabled reaction of Al–Ga and Al–Ga–In–Sn alloys with water. Int. J. Hydrogen Energy 2011; 36(9): 5271‐5279.
  • [11] Chen XY, Zhao ZW, Hao MM, Wang DZ. Research of hydrogen generation by the reaction of Al-based materials with water. J. Power Sources 2013; 222: 188-195.
  • [12] Macanás J, Soler L, Candela AM, Muñoz M, Casado J. Hydrogen generation by aluminum corrosion in aqueous alkaline solutions of inorganic promoters: the AlHidrox process. Energy. 2011; 36(5):2493‐2501.
  • [13] Czech E, Troczynski T. Hydrogen generation through massive corrosion of deformed aluminum in water. Int. J. Hydrogen Energy 2010; 35: 1029-1037.
  • [14] Rong S, Baozhong Z, Yunlan S. The effect of NiCl2 and Na2CO3 on hydrogen production by Al/H2O system. Int. J. Hydrogen Energy 2017; 42: 3586-3592.
  • [15] Rosenband V, Gany A. Application of activated aluminum powder for generation of hydrogen from water Int. J. Hydrogen Energy 2010; 35: 10898-10904.
  • [16] Deng Z-Y, Ferreira J, Sakka Y. Hydrogen‐Generation Materials for Portable Applications. J. Am. Ceram. Soc. 2008; 91(12): 3825 – 3834.
  • [17] Chen XY, Zhao ZW, Hao MM, Wang DZJ. Research of hydrogen generation by the reaction of Al-based materials with water. J. Power Sources 2013; 222: 188–195.
  • [18] Fan MQ, Mei DS, Chen D, Lv CJ, Shu KY. Portable hydrogen generation from activated Al-Li-Bi alloys in water. Renewable Energy 2011; 36(11): 3061-3067.
  • [19] Li, R., Fang, Y., Yang, T., Sun, Y., Li, Y., 2011. Influence Factor of hydrogen generation from aluminum-water reaction. In: 2011 International conference on Computer distributed Control and Intelligent Environmental Monitoring; 19-20 Feb. 2011; Changsha, China. IEEE. pp. 852-855.
  • [20] Soler L, Macanas J, Munoz M, Casado J, Aluminum and aluminum alloys as sources of hydrogen for fuel cell applications. J. Power Sources 2007; 169: 144–149.
There are 20 citations in total.

Details

Primary Language English
Journal Section Research Article
Authors

Sevim Yolcular Karaoğlu 0000-0003-0954-6889

Publication Date October 16, 2020
Acceptance Date August 13, 2020
Published in Issue Year 2020 Volume: 5 Issue: 2

Cite

APA Yolcular Karaoğlu, S. (2020). EFFECT OF ALKALINE CONCENTRATION ON THE HYDROGEN GENERATION. The International Journal of Energy and Engineering Sciences, 5(2), 34-42.

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