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Investigation and Improvement of Thermal and Mechanical Properties of Recycled Polypropylene / Oxidized Polyethylene Composites

Year 2024, Volume: 17 Issue: 1, 69 - 79, 28.03.2024

Erhan Demircan Betül Gülgeç Hakan Akat

https://doi.org/10.18185/erzifbed.1315542

Abstract

In this study, various composites were prepared from synthetic wastes with oxidized polyolefin (OxPO) and the mechanical (elongation, elasticity, tensile strength, etc.) of these composites.) and discusses the results of an experimental study on its thermal characterization. The oxidized polyolefin/Styrene (St) mixture was infused with the melt free radical polymerization method on recycled polypropylene (rPP). The effect of the initial monomer concentration on the mechanical properties of recycled polypropylene was investigated. The mechanical (elongation and tensile strength) properties of the composites produced were made according to the ISO 527-2 standard method. It has been observed that the tensile strength and elongation, which are the mechanical properties of (OxPO/St)/rPP composites, increase compared to RPP. The resulting polymers were then characterized by Fourier transformational infrared spectroscopy (FTIR).

Keywords

Polypropylene oxidized polyethylene; composite; styrene; recycle

Supporting Institution

TÜBİTAK -BAP

Project Number

119C140-FDK-2012-23124,

References

  • [1] Tapkire G., Parihar S., Patil P., and Kumavat H. R., (2014) Recycling plastic used in concrete paver, International Journal of Research in Engineering and Technology, 3(9), 33-35.
  • [2] Jassim A. K., (2017) Recycling of polyethylene waste to produce plastic cement, Elsevier, Procedia Manufacturing, 8, 635-642.
  • [4] Asl, D. H., Abdouss, M., Angaji, T. M., Haji, A., (2013) Chem. Ind. Chem. Eng., 19 (3), 441-448.
  • [5] Awad, S., Khalaf, E., (2017) Improvement, the Performance of Polyurethane (PUR), Y-290 Resin as Coating of Oil Pipeline by Using Multi-Walled Carbon Nanotubes (MWCNTs), Engineering and Technology Journal, 35, 845- 848.
  • [6] Arcana, I M., Bundjali, B., Yudistira, I., Jariah, B., and Sukria, L., (2007) Study on Properties of Polymer Blends from Polypropylene with Polycaprolactone and Their Biodegradability, Polymer Journal, Vol.39, No.12., 1337-1344.
  • [7] Chung, T.C., and Rhubright, D., (1993) Functionalization of polypropylene by hydroboration, Polym. Sci., Part A: Polym. Chem., 31 (11), 2759-2763.
  • [8] Chung, T.C., and Rhubright, D., (1994) Polypropylene-graft-Polycaprolactone: Synthesis and Applications in Polymer Blends, Macromolecules 27, 1313-1319.
  • [9] Bataille, P., Boisse, S., and Schreiber, H., (1987) Mechanical properties and permeability of polypropylene and poly(ethylene terephthalate) mixtures, Polym. Eng. Sci., 27(9), 622-626.
  • [10] Harris, M., Potgieter, J., Ray, S., Archer, R., and Arif, K. M., (2019) Acrylonitrile Butadiene Styrene and Polypropylene Blend with Enhanced Thermal and Mechanical Properties for Fused Filament Fabrication, MDPI, 12(24), 4167.
  • [11] Li, Y., Jia, S., Du, S., Wang, Y., Lv, L., Zhang, J., (2018) Improved properties of recycled polypropylene by introducing the long chain branched structure through reactive extrusion, Elsevier, Waste Management, 76, 172-179.
  • [12] Srivabut, C., Ratanawilai, T., Hiziroglu, S., (2017) Effect of nanoclay, talcum, and calcium carbonate as filler on properties of composites manufactured from recycled polypropylene and rubberwood fiber, Elsevier, Construction and Building Materials, 162, 450-458.
  • [13] Gijsman, P., Hennekens, J., (1993) The mechanism of the low-temperature oxidation of polypropylene, Polymer Degradation and Stability, 42, 95-105.
  • [14] Seven, M. K., Wheeler, M. R., (2009) Method for preparing oxidized polyolefin waxes, US Patent No. US 7.622,031 B2.
  • [15] Seven, K., (2007) Method for preparing oxidized polyolefin waxes, WO Patents.
  • [16] Qu, J., (1993) The effect of slightly weakened interfaces on the overall elastic properties of composite materials, Elsevier, Mechanics of Materials, 14(4), 269-281.
  • [17] Rosato, D. V., (1997) Designing with reinforced composites, Hanser Gardner Publications, New York.
  • [18] Vasiliev, V. V., Morozov, E. V., (2001) Mechanics and analysis of composite materials, Elsevier Pub.
  • [19] Moad, G., (1999) The synthesis of polyolefin graft copolymers by reactive extrusion, Progress in Polymer Science, 24, 81–142.

Year 2024, Volume: 17 Issue: 1, 69 - 79, 28.03.2024

Erhan Demircan Betül Gülgeç Hakan Akat

https://doi.org/10.18185/erzifbed.1315542

Abstract

Project Number

119C140-FDK-2012-23124,

References

  • [1] Tapkire G., Parihar S., Patil P., and Kumavat H. R., (2014) Recycling plastic used in concrete paver, International Journal of Research in Engineering and Technology, 3(9), 33-35.
  • [2] Jassim A. K., (2017) Recycling of polyethylene waste to produce plastic cement, Elsevier, Procedia Manufacturing, 8, 635-642.
  • [4] Asl, D. H., Abdouss, M., Angaji, T. M., Haji, A., (2013) Chem. Ind. Chem. Eng., 19 (3), 441-448.
  • [5] Awad, S., Khalaf, E., (2017) Improvement, the Performance of Polyurethane (PUR), Y-290 Resin as Coating of Oil Pipeline by Using Multi-Walled Carbon Nanotubes (MWCNTs), Engineering and Technology Journal, 35, 845- 848.
  • [6] Arcana, I M., Bundjali, B., Yudistira, I., Jariah, B., and Sukria, L., (2007) Study on Properties of Polymer Blends from Polypropylene with Polycaprolactone and Their Biodegradability, Polymer Journal, Vol.39, No.12., 1337-1344.
  • [7] Chung, T.C., and Rhubright, D., (1993) Functionalization of polypropylene by hydroboration, Polym. Sci., Part A: Polym. Chem., 31 (11), 2759-2763.
  • [8] Chung, T.C., and Rhubright, D., (1994) Polypropylene-graft-Polycaprolactone: Synthesis and Applications in Polymer Blends, Macromolecules 27, 1313-1319.
  • [9] Bataille, P., Boisse, S., and Schreiber, H., (1987) Mechanical properties and permeability of polypropylene and poly(ethylene terephthalate) mixtures, Polym. Eng. Sci., 27(9), 622-626.
  • [10] Harris, M., Potgieter, J., Ray, S., Archer, R., and Arif, K. M., (2019) Acrylonitrile Butadiene Styrene and Polypropylene Blend with Enhanced Thermal and Mechanical Properties for Fused Filament Fabrication, MDPI, 12(24), 4167.
  • [11] Li, Y., Jia, S., Du, S., Wang, Y., Lv, L., Zhang, J., (2018) Improved properties of recycled polypropylene by introducing the long chain branched structure through reactive extrusion, Elsevier, Waste Management, 76, 172-179.
  • [12] Srivabut, C., Ratanawilai, T., Hiziroglu, S., (2017) Effect of nanoclay, talcum, and calcium carbonate as filler on properties of composites manufactured from recycled polypropylene and rubberwood fiber, Elsevier, Construction and Building Materials, 162, 450-458.
  • [13] Gijsman, P., Hennekens, J., (1993) The mechanism of the low-temperature oxidation of polypropylene, Polymer Degradation and Stability, 42, 95-105.
  • [14] Seven, M. K., Wheeler, M. R., (2009) Method for preparing oxidized polyolefin waxes, US Patent No. US 7.622,031 B2.
  • [15] Seven, K., (2007) Method for preparing oxidized polyolefin waxes, WO Patents.
  • [16] Qu, J., (1993) The effect of slightly weakened interfaces on the overall elastic properties of composite materials, Elsevier, Mechanics of Materials, 14(4), 269-281.
  • [17] Rosato, D. V., (1997) Designing with reinforced composites, Hanser Gardner Publications, New York.
  • [18] Vasiliev, V. V., Morozov, E. V., (2001) Mechanics and analysis of composite materials, Elsevier Pub.
  • [19] Moad, G., (1999) The synthesis of polyolefin graft copolymers by reactive extrusion, Progress in Polymer Science, 24, 81–142.
There are 18 citations in total.

Details

Primary Language English
Subjects Physical Properties of Materials
Journal Section Makaleler
Authors

Erhan Demircan 0000-0002-5363-3835

Betül Gülgeç This is me 0009-0002-4922-0795

Hakan Akat 0000-0003-4002-5352

Project Number 119C140-FDK-2012-23124,
Early Pub Date March 27, 2024
Publication Date March 28, 2024
Published in Issue Year 2024 Volume: 17 Issue: 1

Cite

APA Demircan, E., Gülgeç, B., & Akat, H. (2024). Investigation and Improvement of Thermal and Mechanical Properties of Recycled Polypropylene / Oxidized Polyethylene Composites. Erzincan University Journal of Science and Technology, 17(1), 69-79. https://doi.org/10.18185/erzifbed.1315542
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